SAFETY DATA NTAWV

Raws li UN GHS hloov kho 8

Version: 1.0

Hnub tsim: Lub Xya Hli 15, 2019

Hloov Kho Hnub: Lub Xya Hli 15, 2019

QHIA 1: Kev Qhia

1.1 GHS Cov khoom lag luam

1.2 Lwm yam kev txheeb xyuas

1.3 Pom zoo siv cov tshuaj thiab txwv kev siv

1.4 Supplier cov ntsiab lus

1.5 Tus xov tooj xwm ceev

QHOV 2: Kev txheeb xyuas qhov xwm txheej

2.1 Kev faib tawm ntawm cov khoom lossis sib xyaw

Flammable kua, Qeb 1

Mob toxicity – Qeb 3, Qhov ncauj

Mob toxicity – Qeb 3, Dermal

Cov tawv nqaij khaus, Qeb 2

Qhov muag khaus, Qeb 2

Mob toxicity – Qeb 2, Inhalation

Lub hom phiaj tshwj xeeb ntawm lub cev toxicity – ib zaug raug, Qeb 3

Kev phom sij rau cov dej nyob ib puag ncig, luv luv (Acute) - Qeb Mob 1

Kev phom sij rau cov dej nyob ib puag ncig, mus sij hawm ntev (Chronic) - Qeb 1 Chronic

2.2GHS daim ntawv lo ntsiab lus, suav nrog cov lus ceeb toom

2.3 Lwm yam kev phom sij uas tsis ua rau kev faib tawm

tsis muaj ntaub ntawv

QHOV 3: Cov khoom xyaw / cov ntaub ntawv ntawm cov khoom xyaw

3.1 Khoom

QHIA 4: Kev pab ua ntej

4.1 Kev piav qhia txog qhov tsim nyog tau txais kev pab thawj zaug

Yog nqus tau

Huab cua ntshiab, so. Ib nrab-upright txoj hauj lwm. Xa mus rau kev kho mob.

Ua raws li daim tawv nqaij

Tshem cov khaub ncaws tsis huv. Yaug daim tawv nqaij nrog dej ntau los yog da dej. Xa mus rau kev kho mob.

Tom qab qhov muag pom

Yaug nrog dej kom ntau rau ob peb feeb (tshem cov lo ntsiab muag yog tias ua tau yooj yim). Xa mus rau kev kho mob tam sim ntawd.

Tom qab noj

Yaug qhov ncauj. Tsis txhob ua rau ntuav. Muab ib los yog ob khob dej haus. Xa mus rau kev kho mob.

4.2 Cov tsos mob tseem ceeb tshaj plaws / cuam tshuam, mob hnyav thiab qeeb

Excerpt los ntawm ERG Guide 131 [Flammable Liquids - Toxic]: TOXIC; Tej zaum yuav ua rau tuag taus yog tias nqus tau, noj lossis nqus los ntawm daim tawv nqaij. Kev nqus tau los yog sib cuag nrog qee yam ntawm cov khoom no yuav ua rau khaus lossis hlawv tawv nqaij thiab qhov muag. Hluav taws yuav ua rau khaus, corrosive thiab/los yog cov pa phem. Vapors tuaj yeem ua rau kiv taub hau lossis ua tsis taus pa. Cov dej ntws los ntawm kev tswj hluav taws kub lossis dej dilution tuaj yeem ua rau muaj kuab paug. (ERG, 2016)

4.3 Qhia txog kev kho mob tam sim ntawd thiab kev kho mob tshwj xeeb, yog tias tsim nyog

Kev pab thawj zaug tam sim ntawd: Xyuas kom meej tias kev tshem tawm kom txaus tau ua tiav. Yog tias tus neeg mob tsis ua pa, pib ua pa tawm dag zog, zoo dua nrog kev thov-valve resuscitator, hnab-valve-mask device, lossis hnab tshos daim npog ntsej muag, raws li tau kawm. Ua CPR raws li qhov tsim nyog. Tam sim ntawd yaug qhov muag tsis huv nrog dej maj mam ntws. Tsis txhob ua rau ntuav. Yog tias ntuav tshwm sim, ntswj tus neeg mob rau pem hauv ntej lossis tso rau sab laug (lub taub hau-down, yog tias ua tau) kom tswj tau txoj hlab pa qhib thiab tiv thaiv kev nqhis dej. Cia tus neeg mob nyob ntsiag to thiab tswj lub cev kub. Tau txais kev kho mob. Ketones thiab lwm yam sib xyaw

QHIA 5: Kev ntsuas hluav taws kub

5.1 Tsim nyog tua cov xov xwm

Yog tias cov khoom siv hluav taws kub los yog cuam tshuam nrog hluav taws: Tsis txhob tua hluav taws tshwj tsis yog tias ntws tuaj yeem nres. Kev tua hluav taws siv tus neeg sawv cev tsim nyog rau hom hluav taws kub nyob ib puag ncig. (Cov khoom nws tus kheej tsis hlawv lossis kub hnyiab nrog qhov nyuaj.) Txias tag nrho cov ntim uas cuam tshuam nrog dej nyab. Siv dej kom deb li deb tau. Siv ua npuas ncauj, tshuaj qhuav qhuav, lossis carbon dioxide. Khaws cov dej ntws tawm ntawm cov kav dej thiab cov dej ntws. Chloroacetone, stabilized

5.2 Cov teeb meem tshwj xeeb tshwm sim los ntawm cov tshuaj

Tshaj tawm los ntawm ERG Guide 131 [Flammable Liquids - Toxic]: HIGHLY FLAMMABLE: Yuav tau yooj yim ignited los ntawm tshav kub, sparks los yog nplaim taws. Cov vapors tuaj yeem tsim cov khoom tawg nrog cua. Vapors tuaj yeem mus rau qhov chaw ntawm qhov hluav taws kub thiab rov qab flash. Feem ntau cov vapors hnyav dua li huab cua. Lawv yuav kis tau mus rau hauv av thiab sau rau hauv qhov chaw qis lossis qhov chaw kaw (sewers, hauv qab daus, tanks). Vapor explosion thiab tshuaj lom phom sij nyob rau hauv tsev, sab nraum zoov los yog hauv cov kav dej phwj tuaj. Cov tshuaj uas tsim los nrog (P) tuaj yeem polymerize tawg thaum cua sov lossis koom nrog hluav taws. Cov dej ntws mus rau hauv cov kav dej yuav ua rau muaj hluav taws kub lossis tawg. Cov thawv ntim khoom tuaj yeem tawg thaum cua sov. Cov kua dej ntau yog sib dua li dej. (TSI, 2016)

5.3 Kev tiv thaiv tshwj xeeb rau cov neeg tua hluav taws

Siv cov tshuaj tsuag dej, hmoov, dej cawv-resistant ua npuas ncauj, carbon dioxide. Thaum muaj hluav taws kub: khaws cov nruas, thiab lwm yam, txias los ntawm txau nrog dej.

QHOV 6: Kev ntsuas kev tso tawm tsis raug cai

6.1 Kev ceev faj tus kheej, cov cuab yeej tiv thaiv thiab cov txheej txheem xwm txheej ceev

Tshem tag nrho cov khoom siv hluav taws xob. Tshem tawm qhov chaw txaus ntshai! Tham nrog tus kws tshaj lij! Kev tiv thaiv tus kheej: lim lub tshuab ua pa rau cov pa roj carbon monoxide thiab cov vapors yoog raws huab cua concentration ntawm cov khoom. Qhov cua. Sau cov kua dej tawm hauv cov thawv ntim. Absorb cov kua seem hauv cov xuab zeb lossis inert absorbent. Tom qab ntawd khaws thiab pov tseg raws li cov cai hauv zos.

6.2 Kev ceev faj ib puag ncig

Tshem tag nrho cov khoom siv hluav taws xob. Tshem tawm qhov chaw txaus ntshai! Tham nrog tus kws tshaj lij! Kev tiv thaiv tus kheej: lim lub tshuab ua pa rau cov pa roj carbon monoxide thiab cov vapors yoog raws huab cua concentration ntawm cov khoom. Qhov cua. Sau cov kua dej tawm hauv cov thawv ntim. Absorb cov kua seem hauv cov xuab zeb lossis inert absorbent. Tom qab ntawd khaws thiab pov tseg raws li cov cai hauv zos.

6.3 Cov txheej txheem thiab cov khoom siv rau kev ntim thiab tu

Kev xav txog ib puag ncig - av nchuav: khawb ib lub qhov, pas dej, pas dej, tuav thaj chaw kom muaj cov kua lossis cov khoom siv. / SRP: Yog tias lub sijhawm tso cai, lub pits, pas dej, pas dej da dej, qhov chaw ntub dej, lossis cov chaw tuav yuav tsum tau muab ntim nrog cov ntaub ntawv tsis muaj dej tsis zoo. Absorb tej kua nrog ya tshauv, cement hmoov, los yog coj mus muag sorbents. Chloroacetone, stabilized

QHIA 7: Kev tuav thiab khaws cia

7.1 Kev ceev faj rau kev nyab xeeb

Tsis muaj nplaim taws, tsis muaj dab tsi thiab tsis haus luam yeeb. Tshaj 35 ° C siv lub kaw lus kaw, qhov cua thiab cov khoom siv hluav taws xob tawg. Tuav nyob rau hauv qhov chaw zoo ventilated. Hnav khaub ncaws tiv thaiv kom haum. Tsis txhob kov ntawm daim tawv nqaij thiab qhov muag. Tsis txhob tsim cov hmoov av thiab aerosols. Siv cov cuab yeej tsis muaj teeb meem. Tiv thaiv hluav taws los ntawm electrostatic tawm chav.

7.2 Cov xwm txheej kom muaj kev nyab xeeb, suav nrog txhua qhov tsis sib xws

Khaws tsuas yog tias ruaj khov. Hluav taws kub. Sib cais los ntawm cov muaj zog oxidants thiab zaub mov thiab khoom noj. Khaws rau hauv qhov tsaus ntuj.Khoos tsuas yog tias ruaj khov. Hluav taws kub. Sib cais los ntawm cov muaj zog oxidants, khoom noj khoom haus thiab khoom noj. Khaws nyob rau hauv qhov tsaus ntuj… Siab tshaj 35 ° C siv lub kaw lus kaw, qhov cua, thiab cov khoom siv hluav taws xob tawg.

QHOV TSEEB 8: Kev tswj kom raug/kev tiv thaiv tus kheej

8.1Control parameters

Kev ua haujlwm raug txwv qhov nqi

TLV: 1 ppm as STEL; (daim tawv nqaij)

Cov khoom siv roj ntsha txwv

tsis muaj ntaub ntawv

8.2 Tsim nyog engineering tswj

Xyuas kom muaj qhov cua txaus. Ua raws li kev ua haujlwm huv huv thiab kev nyab xeeb. Teeb tsa kev tawm thaum muaj xwm txheej ceev thiab thaj chaw muaj kev pheej hmoo tshem tawm.

8.3 Kev tiv thaiv tus kheej, xws li cov cuab yeej tiv thaiv tus kheej (PPE)

Qhov muag / ntsej muag tiv thaiv

Hnav daim npog ntsej muag lossis qhov muag tiv thaiv ua ke nrog kev tiv thaiv ua pa.

Tiv thaiv daim tawv nqaij

Cov hnab looj tes tiv thaiv. Cov khaub ncaws tiv thaiv.

Kev tiv thaiv ua pa

Siv qhov cua, tso pa hauv zos lossis tiv thaiv ua pa.

Kev kub ntxhov

tsis muaj ntaub ntawv

QHIA 9: Lub cev thiab tshuaj lom neeg thiab cov yam ntxwv ntawm kev nyab xeeb

QHIA 10: Stability thiab reactivity

10.1 Reactivity

Cov tshuaj maj mam polymerizes nyob rau hauv tus ntawm lub teeb. Qhov no ua rau hluav taws kub lossis tawg phom sij. Decomposes ntawm cua sov thiab hlawv.

10.2 Chemical stability

Tig tsaus nti thiab resinifies ntawm lub teeb pom kev ntev, tej zaum yuav ruaj khov los ntawm 0.1% dej lossis 1.0% calcium carbonate.

10.3 Muaj peev xwm ua rau muaj kev phom sij

Flammable thaum raug tshav kub los yog nplaim taws, los yog oxidizers.CHLOROACETONE tig tsaus nti thiab resinifies ntawm lub teeb raug mus ntev [Merck]. Qhov no tshwm sim nyob rau hauv ib lub raj mis thaum lub sij hawm cia rau ob xyoos ntawm ib tug txee nyob rau hauv diffused teeb. Ob peb hnub tom qab lub raj mis txav mus, nws tawg [Ind. Eng. Xov Xwm 9:184(1931)]. Nws ruaj khov los ntawm kev ntxiv 0.1% dej lossis 0.1% CaCO3.

10.4 Cov xwm txheej kom zam

tsis muaj ntaub ntawv

10.5 Cov ntaub ntawv tsis sib xws

CHEMICAL PROFILE: Tus kheej-reactive. Chloroacetone tau tig dub thaum khaws cia rau ob xyoos ntawm nws tus kheej hauv lub teeb diffused. Ob peb hnub tom qab lub raj mis ntawm chloroacetone tau txav mus, nws tawg. Cov chloroacetone tau polymerized rau hauv cov khoom zoo li dub, Ind. Eng. Xov Xwm 9:184(1931). (REACTIVITY, 1999)

10.6 Cov khoom tsim kev puas tsuaj

Thaum rhuab mus rau decomposition nws emits cov pa phem heev.

QHOV 11: Cov ntaub ntawv toxicological

Mob toxicity

• Qhov ncauj: LD50 Rat qhov ncauj 100 mg / kg
• Inhalation: LC50 Rat inhalation 262 ppm / 1 hr
• Dermal: tsis muaj ntaub ntawv muaj

Cov tawv nqaij corrosion / khaus

tsis muaj ntaub ntawv

Kev puas tsuaj qhov muag loj / khaus

tsis muaj ntaub ntawv

Ua pa los yog tawv nqaij rhiab heev

tsis muaj ntaub ntawv

Kab mob cell mutagenicity

tsis muaj ntaub ntawv

Carcinogenicity

tsis muaj ntaub ntawv

Kev tsim tawm toxicity

tsis muaj ntaub ntawv

STOT-ib qhov raug

Lachrymation. Cov tshuaj no mob heev rau lub qhov muag, tawv nqaij thiab ua pa ib ntsuj av.

STOT-repeated exposure

tsis muaj ntaub ntawv

Aspiration txaus ntshai

Cov huab cua tsis zoo tuaj yeem ncav cuag sai heev ntawm evaporation ntawm cov khoom no ntawm 20 ° C.

QHOV 12: Cov ntaub ntawv Ecological

12.1 Toxicity

• Toxicity rau ntses: tsis muaj ntaub ntawv
• Toxicity rau daphnia thiab lwm yam dej invertebrates: tsis muaj ntaub ntawv
• Toxicity rau algae: tsis muaj ntaub ntawv muaj
• Toxicity rau microorganisms: tsis muaj ntaub ntawv

12.2 Kev ua siab ntev thiab degradability

tsis muaj ntaub ntawv

12.3 Bioaccumulative muaj peev xwm

Qhov kwv yees BCF ntawm 3 tau suav nrog hauv cov ntses rau 1-chloro-2-propanone (SRC), siv qhov kwv yees kwv yees Kow ntawm 0.02(1) thiab qhov sib npaug ntawm qhov sib npaug (2). Raws li cov txheej txheem kev faib tawm (3), BCF no qhia txog lub peev xwm rau bioconcentration hauv cov kab mob hauv dej tsawg (SRC).

12.4Mobility hauv av

Siv cov qauv kev kwv yees raws li kev sib txuas ntawm molecular indices (1), Koc ntawm 1-chloro-2-propanone tuaj yeem kwv yees li 5 (SRC). Raws li cov txheej txheem kev faib tawm (2), qhov kwv yees tus nqi Koc no qhia tias 1-chloro-2-propanone yuav tsum muaj kev txav mus los hauv av.

12.5 Lwm yam teebmeem

tsis muaj ntaub ntawv

QHIA 13: Kev txiav txim siab pov tseg

13.1 Cov txheej txheem pov tseg

Khoom

Cov khoom tuaj yeem muab pov tseg los ntawm kev tshem tawm mus rau lub chaw pov tseg tshuaj tua kab mob lossis los ntawm kev tswj incineration nrog flue gas scrubbing. Tsis txhob paug dej, khoom noj, pub los yog noob los ntawm kev cia lossis pov tseg. Tsis txhob tso tawm rau cov kav dej phwj tuaj.

Kev ntim khoom tsis huv

Cov thawv ntim tau triply yaug (lossis sib npaug) thiab muab rau kev rov ua dua lossis rov kho dua. Xwb, lub ntim tuaj yeem punctured kom nws siv tsis tau rau lwm lub hom phiaj thiab tom qab ntawd muab pov tseg rau hauv qhov chaw huv huv. Tswj incineration nrog flue roj txhuam yog ua tau rau cov khoom ntim uas muaj hluav taws kub.

QHIA 14: Cov ntaub ntawv thauj mus los

14.1 UN Nr

14.2 UN Proper Shipping Lub Npe

14.3 Tsheb thauj neeg mob cov chav kawm (es)

14.4Packing pab pawg, yog tias muaj

14.5 Kev puas tsuaj ib puag ncig

14.6 Kev ceev faj tshwj xeeb rau cov neeg siv

tsis muaj ntaub ntawv

14.7 Thauj khoom ntau raws li IMO cov cuab yeej

tsis muaj ntaub ntawv

QHIA 15: Cov ntaub ntawv tswj hwm

15.1 Kev nyab xeeb, kev noj qab haus huv thiab ib puag ncig cov cai tshwj xeeb rau cov khoom hauv nqe lus nug

QHIA 16: Lwm cov ntaub ntawv

Cov ntaub ntawv ntawm kev kho dua tshiab

Abbreviations thiab acronyms

• CAS: Chemical Abstracts Service
• ADR: Daim ntawv cog lus European hais txog International Carriage of Dangerous Goods by Road
• RID: Txoj cai hais txog International Carriage of Dangerous Goods by Rail
• IMDG: International Maritime Dangerous Khoom
• IATA: International Air Transportation Association
• TWA: Time Weighted Average
• STEL: Lub sijhawm luv luv raug txwv
• LC50: Lethal Concentration 50%
• LD50: Ua kom tuag 50%
• EC50: Ua kom pom tseeb 50%
• IPCS - Daim Npav Kev Nyab Xeeb Thoob Ntiaj Teb (ICSC), lub vev xaib: http://www.ilo.org/dyn/icsc/showcard.home
• HSDB – Hazardous Substances Data Bank, lub vev xaib: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
• IARC - Lub Chaw Haujlwm Thoob Ntiaj Teb rau Kev Tshawb Fawb Txog Kab Mob, lub vev xaib: http://www.iarc.fr/
• eChemPortal - Lub Ntiaj Teb Portal rau Cov Lus Qhia Txog Tshuaj Tshuaj los ntawm OECD, lub vev xaib: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
• CAMEO Chemicals, lub vev xaib: http://cameochemicals.noaa.gov/search/simple
• ChemIDplus, lub vev xaib: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
• ERG – Phau Ntawv Qhia Txog Thaum Muaj Xwm Ceev los ntawm US Department of Transportation, lub vev xaib: http://www.phmsa.dot.gov/hazmat/library/erg
• Lub teb chaws Yelemees GESTIS-database ntawm cov khoom phom sij, lub vev xaib: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
• ECHA - European Chemicals Agency, lub vev xaib: https://echa.europa.eu/

Cov ntaub ntawv

Lwm cov ntaub ntawv

Tom qab kev sib cuag nrog cov kua hlwv tsim tuaj yeem ncua mus txog rau ob peb teev dhau los. Cov kev txwv tsis pub muaj pov thawj hauv cov ntaub ntawv, txawm hais tias cov khoom siv hluav taws xob yog hluav taws kub thiab muaj qhov taw tes ntawm qhov kub <61 ° C.Qhov kev txwv ntawm kev ua haujlwm yuav tsum tsis pub tshaj thaum lub sij hawm ib feem ntawm Kev ua haujlwm raug.Cov ntxhiab ceeb toom thaum tus nqi raug txwv tsis txaus.Ib qho ntxiv stabilizer lossis inhibitor tuaj yeem cuam tshuam cov khoom toxicological ntawm cov khoom no; nrog tus kws tshaj lij.

Cov lus nug txog SDS no, Thov xa koj qhov kev nug rauinfo@mit-ivy.com